Infrared Absorption Spectroscopy (IR)
IR spectroscopy is the measurement of the wavelength and intensity of the absorption of mid-infrared light by a sample. Mid-infrared light (2.5 - 50 Ám, 4000 - 200 cm-1) is energetic enough to excite molecular vibrations to higher energy levels. The wavelength of IR absorption bands are characteristic of specific types of chemical bonds, and IR spectroscopy finds its greatest utility for identification of organic and organometallic molecules.
Mechanism of IR absorption
The transition moment for infrared absorption is:
R = < Xi | u | Xj dt >
where Xi and Xj are the initial and final states, respectively, and u is the electric dipole moment operator:
u = uo + (r-re)(du/dr) + ... higher terms.
uo is the permanent dipole moment, which is a constant, and since < Xi | Xj > = 0, R simplifies to:
R = < Xi | (r-re)(du/dr) | Xj >
The result is that there must be a change in dipole moment during the vibration for a molecule to absorb infrared radiation.
Examples of infrared active and inactive absorption bands in CO2
There is no change in dipole moment during the symmetric stretch vibration and the 1340 cm-1 band is not observed in the infrared absorption spectrum (the symmetric stretch is called infrared inactive). There is a change in dipole moment during the asymmetric stretch and the 2350 cm-1 band does absorb infrared radiation (the asymmetric stretch in infrared active). A related vibrational spectroscopic method is Raman spectroscopy, which has a different mechanism and therefore provides complementary information to infrared absorption.
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Copyright © 1996 by Brian M. Tissue